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Reference Electrode, Mercury/Mercury Sulfate, Single Junction

Part Number
RREF0025
Product Discontinued – No Replacement

This product has been discontinued and can no longer be purchased. There is no replacement available at this time. The product remains on our website for reference and a listing of its specifications.

Pine Research suggests purchasing and using standard single junction Ag/AgCl reference electrode instead.

The standard-sized, single junction, mercury/mercury sulfate (Hg2SO4) reference electrode is filled with saturated K2SO4 solution. The internal reference electrode solution, which cannot be accessed or changed, and the external filling solution are the same. The outer filling solution can be refreshed as usual. The additional junction aids to prevent any mercury from reaching bulk solution. The refrerence electrode body is 9.5 mm OD, therefore ideally used with Standard volume electrochemical cells. The reference electrode is designed to be pass through a 14/20 ground glass joint and held in place by the included PTFE adapter, which can be adjusted to control the immersion depth of the reference electrode into the cell. Pine Research recommends proper storage and use of reference electrodes. A variety of useful tools for storage and care are shown below.

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Product Discontinued – No Replacement

This product has been discontinued and can no longer be purchased. There is no replacement available at this time. The product remains on our website for reference and a listing of its specifications.

Pine Research suggests purchasing and using standard single junction Ag/AgCl reference electrode instead.

The standard-sized, single junction, mercury/mercury sulfate (Hg2SO4) reference electrode is filled with saturated K2SO4 solution. The internal reference electrode solution, which cannot be accessed or changed, and the external filling solution are the same. The outer filling solution can be refreshed as usual. The additional junction aids to prevent any mercury from reaching bulk solution. The refrerence electrode body is 9.5 mm OD, therefore ideally used with Standard volume electrochemical cells. The reference electrode is designed to be pass through a 14/20 ground glass joint and held in place by the included PTFE adapter, which can be adjusted to control the immersion depth of the reference electrode into the cell. Pine Research recommends proper storage and use of reference electrodes. A variety of useful tools for storage and care are shown below.

Important
Specifications
References
Documents
SDS
Warning: Product Contains Mercury

To function properly, this electrode necessarily contains a small amount of mercury. The maximum amount of mercury in this electrode is 1.8 grams. Use proper personal protective equipment during use. Store safely. Follow all environmental waste protocols and procedures.

Compatibility Notice

Avoid using this reference electrode with the following: acids, cations that will form insoluble hydroxides, and non-aqueous/organic solvents

Reference Electrodes
Reference chemistry
Hg/HgSO₄
Reference size type
When possible, we add published articles, theses and dissertations, and books to our references library. When we know this product has been used, we will include it in this list below. If you have a reference where our product was used and it's not in this list, please contact us with the details and we will add it.
  1. A. Spencer et al. Participation of electrochemically inserted protons in the hydrogen evolution reaction on tungsten oxides. Chemical Science, 2025, 15, 5385-5402.
Document #
Title
Type
Download
DRP10031
Reference Electrode Storage and Master Reference Electrodes
DRK10053
Overview of Reference Electrode Operation and Alternative Reference Electrodes
For this product, any applicable SDS will be listed here by category. You can view or download the SDS by clicking the appropriate button.
Material Group
Material Name
Actions
Reference Electrode Filling Solutions
Saturated Potassium Sulfate (K₂SO₄)
Reference Electrode Materials
Mercury Sulfate (Hg₂SO₄)
Reference Electrode Materials
Mercury (Hg)

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