Honeycomb Spectroelectrochemistry Cell Kit

Pricing

#	Description	Price in USD
Honeycomb Spectroelectrochemical Cell Kit
AKSTCKIT3	Spectroelectrochemical Cell Kit includes cuvette with cap, one Pt honeycomb electrode, two Au honeycomb electrodes, Universal Specialty Cell Connection Kit, and reference electrode
Spectroelectrochemistry	This cell kit is often purchased as part of a larger spectroelectrochemistry product bundle offered by Pine Research.
List of All Items Included in Kit
AB01STC1AU	Gold Honeycomb Electrode
AB01STC1PT	Platinum Honeycomb Electrode
AB01ESA01	Universal Specialty Cell Connection Kit kit includes circuit board and 1m USB-A to USB Mini-B cable
RRPEAGCL2	Low-Profile Ag/AgCl Reference Electrode 3.5 mm OD x 60 mm L, aqueous gel-filled click here to view all available low-profile reference electrodes
RRPG094	Thin-Layer Quartz Cuvette Cell
AC01STCCAP3	Cuvette Cell Cap
Cell Cables and Accessories (sold separately)
RRTPE05	Compact Voltammetry Cell Cable with Reference Electrode Breakout connects any WaveNow Series potentiostat to a Honeycomb Spectroelectrochemical Cell for use with a separate reference electrode not located on the screen-printed electrode (SPE)
ACP2E09	WaveDriver Mini-USB Cell Cable with Reference Breakout D-shell connector to mini-USB style plug, separate socket for pin connection to a low-profile reference electrode fits cell port on WaveDriver 10/20/40/100/200; this cable is NOT recommended for EIS experiments
RRAVCH2	Honeycomb Spectroelectrochemistry Cuvette Cover COVER ONLY! Does not include honeycomb electrodes, quartz cuvette, or cuvette holder.

Description

Complete Spectroelectrochemistry Cell Kit: The Honeycomb Spectroelectrochemical Cell Kit (AKSTCKIT3) includes 1 quartz cuvette, 1 cell cap, 1 platinum honeycomb electrode, 2 gold honeycomb electrodes, the Universal Specialty Cell Connection Kit, and a low profile Ag/AgCl reference electrode. Our honeycomb electrode chip contains an onboard working, counter and reference electrode. If an alternative reference electrode is needed, we offer a cell cable with a separate reference breakout lead (RRTPE05 for the WaveNow Series and ACP2E09 for the WaveDriver series) used with the WaveNow and WaveDriver respectively where a separate low profile reference electrode fits into the cell cap. Click here for low profile reference electrodes!

Electrode Design: The working electrode is perforated with a honeycomb pattern of holes which allow light to pass through the electrode. The active surface of the working electrode includes a metal coating along the inner walls of the holes. As light passes through the holes, the beam grazes the walls of each hole. Normally the path length of the electrochemically generated species is the diffusion layer near the surface of the electrode. With our honeycomb design the effective path length is the length of the honeycomb card (1.7 mm). As a result, molecules with low extinction coefficients are more easily detectable. Our quartz cuvette is slotted to fit the honeycomb electrode card. The slot also prevents electrogenerated species from diffusing away from the electrode during a spectroelectrochemistry experiment, further improving UV/Vis absorbance.

Universal Compatibility: The honeycomb electrode is screen printed on a ceramic card, allowing it to be used for both aqueous and non-aqueous solvents. The dimensions of our slotted quartz cuvette is 12.5 x 12.5 x 45.0 mm³, which is the standard size for most UV/Vis spectrometer cuvette holders. While Pine Research offers a unique cable that connects the mini-B USB of the honeycomb cell to our WaveNow and WaveDriver potentiostats, we also include a Universal Specialty Cell Connection kit with each Honeycomb cell, for use with any potentiostat.

Documentation

Document Number	Description
Honeycomb Spectroelectrochemistry Cell Kit
DRP10208	Honeycomb Spectroelectrochemical Cell Kit Product Information click here to download (2 MB download)
DRB10074	Spectroelectrochemistry Brochure click here to download (1 MB download)
Universal Specialty Cell Connection Kit
DRP10251	Universal Specialty Cell Connection Kit Product Information click here to download (1 MB download)

Support


Honeycomb Spectroelectrochemistry Cell Kit [AKSTCKIT3]
Paul V. Bernhardt Scanning Optical Spectroelectrochemistry: Applications in Protein Redox Potential Measurements. Chemistry-Methods, 2022. Lee, ChaeHyun; Kim, Kyoungsoo; Shin, YeJi; Han, Donghoon; Yoon, Seog Joon In Situ Spectroelectrochemical Investigation of Perovskite Quantum Dots for Tracking Their Transformation. Front. Energy Res., 2021, 8. Ohui, K.; Babak, M. V.; Darvasiova, D.; Roller, A.; Vegh, D.; Rapta, P.; Guan, G. R. S.; Ou, Y. H.; Pastorin, G.; Arion, V. B. Redox-Active Organoruthenium(II)– and Organoosmium(II)–Copper(II) Complexes, with an Amidrazone–Morpholine Hybrid and [CuICl2]- as Counteranion and Their Antiproliferative Activity. Organometallics, 2019, 38(10), 2307-2318. Dobrov, A.; Darvasiová, D.; Zalibera, M.; Bučinský, L.; Puškárová, I.; Rapta, P.; Shova, S.; Dumitrescu, D.; Martins, L. M. D. R. S.; Pombeiro, A. J. L.; Arion, V. B. Nickel(II) Complexes with Redox Noninnocent Octaazamacrocycles as Catalysts in Oxidation Reactions. Inorg. Chem., 2019, 58(16), 11133-11145. Darvasiová, D.; Šoral, M.; Puškárová, I.; Dvoranová, D.; Vénosová, B.; Bučinský, L.; Zalibera, M.; Dujnič, V.; Dobrov, A.; Schwalbe, M.; Arion, V. B.; Rapta, P. Spectroelectrochemical, photochemical and theoretical study of octaazamacrocyclic nickel(II) complexes exhibiting unusual solvent-dependent deprotonation of methylene group. Electrochim. Acta, 2019, 326, 135006. Piechota, E. J. ; Troian-Gautier, L. ; Sampaio, R. N. ; Brennaman, M. K. ; Hu, K. ; Berlinguette, C. P. ; Meyer, G. J. Optical Intramolecular Electron Transfer in Opposite Directions through the Same Bridge That Follows Different Pathways. J. Am. Chem. Soc., 2018, 140(23), 7176-7186. Barr, T. J. ; Morris, A. J. ; Taheri, A. ; Meyer, G. J. Charge Rectification at Molecular Nanocrystalline TiO2 Interfaces: Overlap Optimization To Promote Vectorial Electron Transfer. The Journal of Physical Chemistry C, 2016, 120(48), 27173-27181. Brady, M. Fundamental Insights into Dye-Sensitized Interfaces for Solar Fuels Production. Ph.D. Dissertation, University of North Carolina at Chapel Hill, Chapel Hill, NC, 2019. Balaraman, L. ; Emhoff, K. A. ; Salem, A. M. ; Hanna, J. ; Alsabony, M. N. ; Bayachou, M. ; Mundell, J. J. ; Christopher Boyd, W. Electrochemical studies of cobalt(II) diphenylazodioxide complexes. Inorg. Chim. Acta, 2020, 501, 119277. Carpenter, J. M. ; Zhong, F. ; Ragusa, M. J. ; Louro, R. O. ; Hogan, D. A. ; Pletneva, E. V. Structure and redox properties of the diheme electron carrier cytochrome c4 from Pseudomonas aeruginosa. J. Inorg. Biochem., 2020, 203, 110889. Zheng, W. ; Tsang, C. ; So, L. Y. ; Liu, M. ; Leung, Y. ; Lee, L. Y. S. Highly efficient stepwise electrochemical degradation of antibiotics in water by in situ formed Cu(OH)2 nanowires. Appl. Catal., B, 2019, 256, 117824. Al-Yasari, A. Synthesis, non-linear optical and electrochemical properties of novel organoimido polyoxometalate derivatives. Ph.D. Dissertation, University of East Anglia, Norwich, United Kingdom, 2016. Ohui, K.; Afanasenko, E.; Bacher, F.; Ting, R. L. X.; Zafar, A.; Blanco-Cabra, N.; Torrents, E.; Dömötör, O.; May, N. V.; Darvasiova, D.; Enyedy, É. A.; Popović-Bijelić, A.; Reynisson, J.; Rapta, P.; Babak, M. V.; Pastorin, G.; Arion, V. B. New Water-Soluble Copper(II) Complexes with Morpholine–Thiosemicarbazone Hybrids: Insights into the Anticancer and Antibacterial Mode of Action. J. Med. Chem., 2019, 62(2), 512-530. E. Büchel, G.; Kossatz, S.; Sadique, A.; Rapta, P.; Zalibera, M.; Bucinsky, L.; Komorovsky, S.; Telser, J.; Eppinger, J.; Reiner, T.; B. Arion, V. cis-Tetrachlorido-bis(indazole)osmium(IV) and its osmium(III) analogues: paving the way towards the cis -isomer of the ruthenium anticancer drugs KP1019 and/or NKP1339. Dalton Trans., 2017, 46(35), 11925-11941. Shova, S.; Vlad, A.; Cazacu, M.; Krzystek, J.; Bucinsky, L.; Breza, M.; Darvasiová, D.; Rapta, P.; Cano, J.; Telser, J.; B. Arion, V. A five-coordinate manganese(III) complex of a salen type ligand with a positive axial anisotropy parameter D. Dalton Trans., 2017, 46(35), 11817-11829. Schorsch, M. ; Kramer, M. ; Goss, T. ; Eisenhut, M. ; Robinson, N. ; Osman, D. ; Wilde, A. ; Sadaf, S. ; Brückler, H. ; Walder, L. ; Scheibe, R. ; Hase, T. ; Hanke, G. T. A unique ferredoxin acts as a player in the low-iron response of photosynthetic organisms. Proceedings of the National Academy of Sciences, 2018, 115(51), E12111-E12120. Orlowska, E. ; Babak, M. V. ; Dömötör, O. ; Enyedy, E. A. ; Rapta, P. ; Zalibera, M. ; Bučinský, L. ; Malček, M. ; Govind, C. ; Karunakaran, V. ; Farid, Y. C. S. ; McDonnell, T. E. ; Luneau, D. ; Schaniel, D. ; Ang, W. H. ; Arion, V. B. NO Releasing and Anticancer Properties of Octahedral Ruthenium–Nitrosyl Complexes with Equatorial 1H-Indazole Ligands. Inorg. Chem., 2018, 57(17), 10702-10717. Shova, S.; Vlad, A.; Cazacu, M.; Krzystek, J.; Ozarowski, A.; Malček, M. ; Bucinsky, L.; Rapta, P.; Cano, J.; Telser, J.; B. Arion, V. Dinuclear manganese(III) complexes with bioinspired coordination and variable linkers showing weak exchange effects: a synthetic, structural, spectroscopic and computation study. Dalton Trans., 2019. Salpage, S. R.; Paul, A.; Som, B.; Banerjee, T.; Hanson, K.; Smith, M. D.; Vannucci, A. K.; Shimizu, L. S. Structural, electrochemical and photophysical properties of an exocyclic di-ruthenium complex and its application as a photosensitizer. Dalton Trans., 2016, 45(23), 9601-9607. Kim, J.; Yennawar, H. P.; Lear, B. J. Synthesis and characterization of ruthenium polypyridyl complexes with hydroxypyridine derivatives: effect of protonation and ethylation at the pyridyl nitrogen. Dalton Trans., 2013, 42(44), 15656-15662. Pazdzior, R.; Yang, Z. (.; Mesbahuddin, M. S.; Yee, J.; van der Est, A.; Rafferty, S. Low reduction potential cytochrome b5 isotypes of Giardia intestinalis. Experimental Parasitology, 2015, 157, 197-201. Adams, R. E.; Schmehl, R. H. Micellar Effects on Photoinduced Electron Transfer in Aqueous Solutions Revisited: Dramatic Enhancement of Cage Escape Yields in Surfactant Ru(II) Diimine Complex/[Ru(NH3)6]2+ Systems. Langmuir, 2016, 32(34), 8598–8607. King, J. D.; McIntosh, C. L.; Halsey, C. M.; Lada, B. M.; Niedzwiedzki, D. M.; Cooley, J. W.; Blankenship, R. E. Metalloproteins Diversified: The Auracyanins Are a Family of Cupredoxins That Stretch the Spectral and Redox Limits of Blue Copper Proteins. Biochemistry, 2013, 52(46), 8267–8275. Kennedy, S. R.; Kozar, M. N.; Yennawar, H. P.; Lear, B. J. Synthesis and characterization of the gold dithiolene monoanion, (Bu4N)[Au(pdt=2,3-pyrazinedithiol)2]. Polyhedron, 2016, 103, 100–104. Zhong, F.; Lisi, G. P.; Collins, D. P.; Dawson, J. H.; Pletneva, E. V. Redox-dependent stability, protonation, and reactivity of cysteine-bound heme proteins. Proceedings of the National Academy of Sciences, 2014, 111(3), E306-E315. Bischof, A. M.; Zhang, S.; Meyer, T. Y.; Lear, B. J. Quantitative Assessment of the Connection between Steric Hindrance and Electronic Coupling in 2,5-Bis(alkoxy)benzene-Based Mixed-Valence Dimers. The Journal of Physical Chemistry C, 2014, 118(24), 12693–12699. Thomsen, J. M.; Sheehan, S. W.; Hashmi, S. M.; Campos, J.; Hintermair, U.; Crabtree, R. H.; Brudvig, G. W. Electrochemical Activation of Cp* Iridium Complexes for Electrode-Driven Water-Oxidation Catalysis. J. Am. Chem. Soc., 2014, 136(39), 13826–13834. Liang, Z.; Kang, M.; Payne, G. F.; Wang, X.; Sun, R. Probing Energy and Electron Transfer Mechanisms in Fluorescence Quenching of Biomass Carbon Quantum Dots. ACS Applied Materials {&} Interfaces, 2016, 8(27), 17478–17488. Zhao, Y.; Vargas-Barbosa, N. M.; Strayer, M. E.; McCool, N. S.; Pandelia, M.; Saunders, T. P.; Swierk, J. R.; Callejas, J. F.; Jensen, L.; Mallouk, T. E. Understanding the Effect of Monomeric Iridium(III/IV) Aquo Complexes on the Photoelectrochemistry of IrOx·nH2O-Catalyzed Water-Splitting Systems. J. Am. Chem. Soc., 2015, 137(27), 8749–8757. Navarathne, D.; Skene, W. G. Towards Electrochromic Devices Having Visible Color Switching Using Electronic Push–Push and Push–Pull Cinnamaldehyde Derivatives. ACS Appl. Mater. Interfaces, 2013, 5(23), 12646–12653. Yang, Z.; Pazdzior, R.; Yee, J.; Rafferty, S. Reduction potential and heme-pocket polarity in low potential cytochrome b5 of Giardia intestinalis. J. Inorg. Biochem., 2016, 158, 110–114. Palmer, J. H.; Lancaster, K. M. Molecular Redox: Revisiting the Electronic Structures of the Group 9 Metallocorroles. Inorg. Chem., 2012, 51(22), 12473–12482. Kellett, C. W.; Swords, W. B.; Turlington, M. D.; Meyer, G. J.; Berlinguette, C. P. Resolving orbital pathways for intermolecular electron transfer. Nat. Commun., 2018, 9(1), 4916. Pourrieux, G.; Abate, P. O.; Vergara, M. M.; Katz, N. E. Redox-induced linkage isomerization detected in [Ru(NH3)5(NVF)](PF6)2(NVF=N-vinylformamide). Inorg. Chem. Commun., 2016, 66, 90-93.

Honeycomb Spectroelectrochemistry Cell Kit [AKSTCKIT3]

Honeycomb Spectroelectrochemistry Cell Kit

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Honeycomb Spectroelectrochemistry Cell Kit

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